MASS-SPECTRAL FRAGMENTATION PATHWAYS IN SOME GLYCOLURIL-TYPE EXPLOSIVES - A STUDY BY COLLISION-INDUCED DISSOCIATION AND ISOTOPE LABELING

J YINON; S BULUSU; T AXENROD; H YAZDEKHASTI

doi:10.1002/oms.1210291109

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MASS-SPECTRAL FRAGMENTATION PATHWAYS IN SOME GLYCOLURIL-TYPE EXPLOSIVES - A STUDY BY COLLISION-INDUCED DISSOCIATION AND ISOTOPE LABELING

Journal article

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MASS-SPECTRAL FRAGMENTATION PATHWAYS IN SOME GLYCOLURIL-TYPE EXPLOSIVES - A STUDY BY COLLISION-INDUCED DISSOCIATION AND ISOTOPE LABELING

J YINON, S BULUSU, T AXENROD and H YAZDEKHASTI

Organic Mass Spectrometry, Vol.29(11), pp.625-631

Nov/1994

DOI: https://doi.org/10.1002/oms.1210291109

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Abstract

Electron impact (EI), chemical ionization and negative-ion chemical ionization (NCI) mass spectra of 1,4-dinitroglycoluril (DINGU), its N-15- and H-2-labeled analogues and the dimethyl-substituted derivatives were recorded. Tandem mass spectrometry with collision induced dissociation was used to study the fragmentation pathways of these compounds. It was found that the main EI fragmentation processes of DINGU are due to the cleavage of C-N bonds and some rearrangement reactions.

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Title: MASS-SPECTRAL FRAGMENTATION PATHWAYS IN SOME GLYCOLURIL-TYPE EXPLOSIVES - A STUDY BY COLLISION-INDUCED DISSOCIATION AND ISOTOPE LABELING
Creators: J YINON (null)
S BULUSU (null)
T AXENROD (null)
H YAZDEKHASTI (null)
Resource Type: Journal article
Publication Details: Organic Mass Spectrometry, Vol.29(11), pp.625-631; Nov/1994
Number of pages: 7
Language: English
DOI: https://doi.org/10.1002/oms.1210291109
Scientific Unit: The Weizmann Institute of Science
Record Identifier: 993265381103596

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